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Tei, C.; Otaka, Masahiko; Kuwahara, Daisuke*
Chemical Physics Letters, 829, p.140755_1 - 140755_6, 2023/10
Times Cited Count:0 Percentile:0.01(Chemistry, Physical)We were able to detect the nuclear magnetic resonance (NMR) signal of a liquid sodium clinging to the interface of solid metal particles for the first time. In this study, we confirmed the difference in the relaxation times due to the difference in the interactions between liquid sodium and metal particles suspended in the liquid sodium. It was found that the surface of the micro titanium particles and liquid metallic sodium interact physically, not chemically.
Itami, Toshio*; Saito, Junichi; Ara, Kuniaki
Metals, 5(3), p.1212 - 1240, 2015/09
Times Cited Count:2 Percentile:4.14(Materials Science, Multidisciplinary)A new kind of suspension liquid was developed by dispersing Ti nanoparticles (10 nm) in liquid Na, which was then determined by TEM (transmission electron microscopy) analysis. The volume fraction was estimated to be 0.0088 from the analyzed Ti concentration (2 at.%) and the densities of Ti and Na. This suspension liquid, Liquid Sodium containing nanoparticles of titanium (LSnanop), shows, despite only a small addition of Ti nanoparticles, many striking features, namely a negative deviation of 3.9% from the ideal solution for the atomic volume, an increase of 17% in surface tension, a decrease of 11% for the reaction heat to water, and the suppression of chemical reactivity to water and oxygen. The decrease in reaction heat to water seems to be derived from the existence of excess cohesive energy of LSnanop. The excess cohesive energy was discussed based on simple theoretical analyses, with particular emphasis on the screening effect. The suppression of reactivity is discussed with the relation to the decrease of heat of reaction to water or the excess cohesive energy, surface tension, the action as a plug of Ti oxide, negative adsorption on the surface of LSnanop, and percolation.
; ; ; Tobita, Tsutomu; Minato, Kazuo; Yamamoto, Katsumune; ;
JAERI-M 87-020, 79 Pages, 1987/02
no abstracts in English
; E.Groos*; J.Rau*
Nuclear Technology, 69, p.368 - 379, 1985/00
Times Cited Count:2 Percentile:37.51(Nuclear Science & Technology)no abstracts in English
; ; ; Minato, Kazuo; Ikawa, Katsuichi; Iwamoto, K.;
JAERI-M 83-232, 67 Pages, 1984/01
no abstracts in English
;
Oyo Butsuri, 30(9), p.635 - 640, 1961/00
no abstracts in English
Suzuki, Reika*; Nakagawa, Taichi; Matsueda, Makoto; Terashima, Motoki; Takase, Tsugiko*; Takagai, Yoshitaka*
no journal, ,
no abstracts in English